![]() ![]() Structure–property relationships (especially in both side chain and backbone engineering) are investigated for a series of poly(tetrathienoacene-diketopyrrolopyrrole) polymers. Understanding the distribution and behavior of both crystalline domains and amorphous regions in conjugated polymer films, upon an applied stress, shall provide general guiding principles to design stretchable organic semiconductors. The design of polymer semiconductors possessing high charge transport performance, coupled with good ductility, remains a challenge. more » This facile method gives insights into the physical nature of amorphous phases in conjugated polymers for better revealing their structure-property relationships, which will guide the designs of new materials with optimized electrical and mechanical properties in the future. Furthermore, the weight fractions of MAF and RAF with various film thicknesses are qualitatively analyzed based on the heat capacity step of each amorphous fraction during the glass transition. The Tgs of diketopyrrolopyrrole-based conjugated polymer thin films are also identified by the same method, with both Tgs showing a decreased value compared to those of bulk samples. Tgs of MAF and RAF increase and decrease with increasing size of fused thiophene units in the backbone, respectively. The detected relaxations were interpreted, in agreement with existing observations in similar systems, as a side-chain relaxation (low temperature), mobile amorphous fractions (MAF), and rigid amorphous fractions (RAF). In this work, alternating current (ac) chip calorimetry and flash differential scanning calorimetry (flash DSC) are applied to successfully identify the Tgs and segmental relaxations of conjugated polymers. Despite some well-developed methods that exist for detecting Tg of conjugated polymers, there is still a need for the combination of advanced calorimetric methodologies to characterize Tg in a broad range of temperatures and scales from bulk to nanometer-thin films. Thomas Aquinas Catholic Church.The glass transition temperature (Tg) of conjugated polymers is a crucial physical parameter that governs their mechanical and electrical properties for applications from sensor technology to skin-like electronics. Pecunia resides in Hattiesburg, Miss., with his wife and their three children. Pecunia is an active member of the American Society of Plastic Surgeons, American College of Surgeons, Southeast Society of Plastic and Reconstructive Surgeons, South Mississippi Medical Society, American Medical Association and the Mississippi State Medical Association.ĭr. He has special interest in cosmetic and breast surgery, as well as body contouring procedures, facial procedures and hand and upper extremity procedures.ĭr. ![]() Pecunia maintains a broad interest in all aspects of plastic surgery. Pecunia has been board certified by the American Board of Plastic Surgery since 1996 and maintains his board certification through the maintenance certification program.ĭr. Pecunia served a general surgery residency at Allegheny General Hospital in Pittsburgh, Pa., He then completed a plastic surgery residency at the University of Mississippi Medical Center in Jackson, Miss., in 1994.ĭr. He then returned to his native New Orleans to attend Louisiana State University School of Medicine, where he received his medical degree in 1986.ĭr. Pecunia received a Bachelor of Science from Louisiana State University in Baton Rouge, La., in 1981. ![]() “We are able to get people immediate results and see their confidence skyrocket.” “I love working in plastics because here, success stories are a daily routine,” Pecunia said. ![]() Pecunia, MD, FACS, joined Hattiesburg Clinic in 1994 and began the department of Plastic Surgery as the clinic’s first plastic and reconstructive surgeon. ![]()
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![]() It’s written by Vicki Quade, one of the creators of the international hit comedy, Late Nite Catechism.įeatured in the New York Times, Bible Bingo is described this way: “The show features improv, Broadway show-tune singalongs, onstage audience-participation quizzes about the Bible and, yes, bingo. Mary Margaret O’Brien, a former nun who now heads a fictitious archdiocese fundraising department. Now in its 13 th year, Bible Bingo is a long-running comedy about the Catholic culture of fundraising and bingo, featuring the character, Mrs. Vicki Quade and Nuns4Fun Entertainment are proud to announce the return of the hit comedy, Bible Bingo, at the Greenhouse Theater Center, Chicago. Lincoln Ave., Chicago.įor more information, go to For tickets at the Greenhouse Theater Center, call the box office at 77, or go online to: Hit Comedy, Bible Bingo, Returns To the Greenhouse Theater Center, Chicagoīingo. Performances are at the Greenhouse Theater Center, 2257 N. Sunday, May 28, celebration will be invited guests only, with a performance by Liz Cloud, and a pre-show party. Saturday, May 27, performance will be open to the public and feature Mary Zentmyer. Our anniversary celebration will take place over two days. In addition, the show has helped raise more than $4 million for the retirement funds of various orders of nuns. Worldwide, the show has grossed more than $100 million in box office receipts. presidents, four Chicago mayors, been performed in at least a dozen Chicago area theaters, hired 20 local actresses, and provided laughter to more than 3.5 million audience members in more than 410 cities, playing in six countries on four continents. Since opening in 1993, Late Nite Catechism has seen three popes, three Chicago cardinals, five U.S. The first and only preview performance was on May 28, 1993, followed the next day, May 29, as the official opening, at Live Bait Theatre in Chicago. She’ll take you back to the days of the Latin Mass, meatless Fridays, and remind you about that good old ruler across the knuckles! You, the audience member, are part of Sister’s class. ![]() The New York Times calls it, “hilarious, well-written and inspired.” Jeffrey Lyons from TV’s Sneak Previews calls Late Nite Catechism “something to savor and enjoy….one of the most intimate, rewarding shows in town.” ![]() The role of Sister, the wise-cracking, lovable character of Late Nite Catechism, was created by Vicki Quade and Maripat Donovan, both products of the Catholic school system. Long-running hits like Late Nite Catechism are a rarity. To get those, use a special code, LNC30, when ordering tickets through the Greenhouse Theater site. ![]() To commemorate the original $8 ticket price, four tickets per performance have been set aside at that original $8 price. JOIN THE FUN! LEGENDARY COMEDY, LATE NITE CATECHISM, CELEBRATES 30 YEARS! TICKETS OFFERED AT ORIGINAL $8 PRICEĪ Chicago original and international hit, Late Nite Catechism turns 30 this month in the city where it all started.įor the entire month of May, a special discount will be offered. ![]() ![]()
![]() ![]() There's a lot of the classic PWAD high pathway / deep depths style a la "Circle of Death" but with tighter confines as befits "ancient" ruins. It's fairly interconnected and centered around an outdoor section that brings to mind the blood trenches of "Watch Your Step" without dwelling on it. This is a wicked cool temple-style level that realizes some of the promise of the original concept's "Hells from all civilizations" idea. The twisting, connecting tunnels and especially knotted western tip feel deliciously Doom 64. The eastern- and westernmost chambers have my favorite fights due to the arachnotron supremacy of the former and the sort of racetrack / cacodemon aspect in the latter. This locale includes blood sewers, hallways lined with jail cells, a subterranean courtyard, and a cool, circular outdoor structure. MAP35 felt slightly more like a "real" place, though, thanks to its outstanding exterior structural detailing. Thematically similar to "Evil Sacrifice" in that you have a brief outdoor area followed by a vast dungeon network. I really appreciated the puzzle in the southern wing, especially since - on its face - it feels like something brand new for this incarnation. The little renderer oddity makes the mechanical room-over-room structures so much more satisfying. This trades the claustrophobia of the originals for more intense player exposure, particularly during the super strong key ambush in the inner yard which has a couple of sneaky pain elementals. The setting feels more spacious than its Doom 64 precursors. It's very pretty though bereft of 1997's rugged charm. The love-letter starts you in the outskirts and has you work your way toward the central keep in order to access the southern and then northern towers. I especially like the fun detail of pouring the same baleful, red light over everything exposed overhead.Ī Kaiser re-take of the nested layer fortress approach of, most obviously, "Altar of Pain" and "Unholy Temple". Kaiser has a lot of fun with the colored lighting, here, giving all of the wall sconces their own particular shades. ![]() I enjoy the scripting since your initial panic at seeing the former is stoked even higher when the floor drops out to level the playing field for the latter. The solid core of pain elementals with an outer ring of arachnotrons makes for something that's still risky to blitz with the nearby, secret BFG. The opening outdoor area looks great with its beams of hanging corpses but the western bit has the biggest brawl. Not that you won't find a few of the latter. This gothic fortress takes the basic theme of "Spawned Fear" and errs toward the side of slaughteryards over dark dungeons. The author isn't quick to throw the hate on but there are tons of zombies, even more imps (normal and nightmare), and cacodemon waves. This is more of an attrition level than anything as far as difficulty goes. I dig the toxic trench, accessed early on, and the architecture of the northwestern area is cool. The architecture is wicked cool and I'm sure that more fun stuff will come given how intimately Kaiser must know the engine's capabilities. It's a complex outing, though, whose navigable layers must be explored via teleporters while the many apertures allow the imp varieties to harry the player. Some of the visuals offer thematic echoes of "Staging Area" and it even shares the same sort of long, winding pathway that links everything together.
![]() ![]() The median sale price of condos also fell by 3.1% on a year-over-year basis to $513,500, the Warren Group figures show. The top-seeded Nuggets are returning to the Western Conference Finals for the second time in four years. At the time of Switzers run, the Amateur Athletics Union (A.A.U.) had yet to formally accept participation of women in long distance running. “They have more money on Wall Street, in stocks, so they might have been a little more gun shy about doing a major home purchase while things were a little chaotic.”įewer condominiums sold last month as well, with just 1,500 transacting compared to the 2,149 in April 2022, a 30.2% decrease. ![]() “The people on the higher end of the market are more affected by things like that,” Norton said. The number of single-family homes sold, 2,897, also dropped last month, by 25.3%, compared to the year before.Ĭassie Norton, associate publisher at the Warren Group, pointed to two driving factors behind the decline: the Fed’s interest rate being at the highest level in 16 years, and the shaky banking industry, with three banks collapsing so far this year. Today, 21 May, 2023 (01 Dhul-Qadah 1444), the Ramadan timings in Boston are in accordance with the sunset and dawn as follows: the Boston Sehri time is. ![]() The median price of a single family home fell 1.2% to $553,500, down from $560,000 in April 2022, according to figures from the Warren Group. Lower priced properties are being sold a lot quicker than those on the high end, bringing down the median sales price, both the Warren Group and Massachusetts Association of Realtors told the Herald on Tuesday. To find out the time difference between Boston and other cities, select the. Time Out Market Boston 401 Park Drive, Boston MA 02215. Inside the expansive space you'll find a best-in-the-city roster, including. The Massachusetts real estate market saw the median sales price for a single-family home drop last month when compared to April 2022, the first year-over-year decline since 2018, according to data released this week by the state’s top market-watchers. Time Out Market Boston spreads out across more than 29,000 square feet of prime Fenway real estate. ![]() ![]() ![]() ![]() Much like the Age of Empires, the formula of building an army, managing resources and conquering the opposing civilizations remains the main focus of the game. Unlike the Age of Empires, which is based on historical events, this game takes place in Atlantis and it focuses on the famous Greek, Egyptian and Norse myths and legends. Command and Conquer: Tiberium AlliancesĮnsemble Studios, who created Age of Empires decided to make a spin-off series based on mythological beliefs.To pass the time till this new game hits the market, check out the following excellent Age of Empires alternatives: While the age classification is the same as previous version of the games, the developers have ensured that the new game will start earlier and finish later than Age of Empires 2. The latest Age of Empire game will cover four different historical ages: After releasing some gameplay footage in 2019, Microsoft announced that the game will release in 2021. After not receiving any love from the developers for quite a while, a new version of Age of Empires was finally unveiled in 2017. Here is our list of 15 cool games similar to Age of Empires:Īge of Empires is one of the best real-time strategy games to be ever released. If you have been looking to get into strategy games or simply are looking for a similar experience to sink your teeth into, then you are the right place. The smarter you are, the bigger the threat you become to your foes. The game allows a player all the freedom to walk their own path and decide how they want to conquer the in-game world. Age of Empires is all about the players forming their own army, managing resources, building their empire and waging a war against opponents to conquer them. ![]() ![]() No need to go to another site to grab the generator, it’s now available as a page on my blog where I can continue to update it at my leisure. you’d like to use colorful text on tumblr ( like this ) but don’t feel like typing in the html code every time same. The third option expands the trait list to add all of the traits from ATICAS, the All Traits in CAS mod, which unlocks many reward traits for the CAS screen. The second option adds all of the traits from various expansion packs. ![]() The first option rolls Basegame traits only. There are now three different ways you can choose to generate the random traits. Just enable ‘Berry prompt’ in the color menu. This means that instead of just the basic ‘blue’ or ‘grey’ for example, you could end up with some neat Berry sim style prompts, such as ‘Tiger’ or ‘Moonstone’. Thanks to I’ve included her Berry Name list as an optional expansion of the colour prompt generation. Now, you can choose to randomize each variable independently, as well as all at once. It has some shiny new features that I think you’re going to love. I’ve rewritten the code for the generator from scratch. My traits include Perfectionist and Hot-Headed. Some would say my most defining feature is my bushy eyebrows. My skintone is medium/dark, my hair is black, and my eyes are grey. Here is an example of what it will create: It also picks a defining feature of their face, so that you can have an idea of where to start on their face sculpting. It includes the basics (such as skin and eye color) and also 2 defining traits (the rest can be up to you) and a colour prompt (for use in their clothing/makeup/etc). This generator will produce very simplistic but helpful ideas for a sim upon the click of a button. So I made a generator for that! This is a new and improved version of my previous generator. The ‘Randomize Sim’ button almost always produces very odd and (to me) unusable sims, and let’s face it, I lack the imagination to come up with 20+ townies from scratch. Support me as an indie developer Help the planet with a donation to nonprofits And more. I sometimes have trouble coming up with unique sims to populate my town as townies/NPCs for my main sims to interact with. Explore more than 10 million color schemes perfect for any project Pro Profile, a new beautiful page to present yourself and showcase your palettes, projects and collections Get advanced PDF export options like shades, hues, color blindness, etc. This can be useful for giving your site or page a consistent look and feel.Pleyita: RANDOM SIM GENERATOR v2 (click here!) This generator is designed to select shades of a given or selected color. Then you can preview the generated color palette and download it in different ways to choose from. With this tool, you can select basic and special colors for your project. (35465c) Get your Html Color codes with our color tools, HEX code, RGB, RGBA, HSL and HSLA values, including HSV, HWB and CMYK. The user-friendly interface provides a wonderful user experience. Tumblr have 1 hex colors that represent their brand. This tool lets you quickly and easily create or import color sets to design your own ideal theme from fully customizable palettes. Supported color schemes: Serial (analog), Monochrome, Triangular, Complementary, Composite, Tints, Free. Need some inspiration? Use the section with ready-made diagrams and save them for your projects. Adjust hues by temperature, saturation, brightness and export to a convenient format (PNG, PDF, SCSS, SVG). Convert, generate palettes, and get any color information RGB 187, 0, 0 CMYK 0, 100, 100, 27 HSL 0°, 100, 36.7 Enter any Hex, RGB or HSL values. Just pick any color and automatically get the perfect combination. This process is quite complex and requires a creative approach. One of the important components of a web designer's work is the creation of a palette, the selection of harmoniously combined colors. How to choose a color scheme if you have no experience in design? Use online generators that combine shades professionally. Signature color will help increase brand awareness by 80%, distinguish you from competitors and gain customer confidence. ![]() ![]() In the Americas, European empires moved more quickly to settlement and territorial control, responding to local demographic and commercial conditions. In Africa and the greater Indian Ocean, nascent European empires consisted mainly of interconnected trading posts and enclaves. Agents of the European powers moved into existing trade networks around the world. Beginning in the 14th Century, there was a decrease in mean temperatures, often referred to as the Little Ice Age, around the world that lasted until the 19th century, contributing to changes in agricultural practices and the contraction of settlement in parts of the Northern Hemisphere.Įmpires expanded and conquered new peoples around the world, but they often had difficulties incorporating culturally, ethnically, and religiously diverse subjects, and administrating widely dispersed territories. New forms of coerced and semi-coerced labor emerged in Europe, Africa, and the Americas, and affected ethnic and racial classifications and gender roles. The Columbian Exchange led to new ways of humans interacting with their environments. Demographic growth - even in areas such as the Americas, where disease had ravaged the population - was restored by the eighteenth century and surged in many regions, especially with the introduction of American food crops throughout the Eastern Hemisphere. Political and economic centers within regions shifted, and merchants’ social status tended to rise in various states. Economic growth also depended on new forms of manufacturing and new commercial patterns, especially in long-distance trade. A surge in agricultural productivity resulted from new methods in crop and field rotation and the introduction of new crops. Let us know which one worked for you in the comments area below.Although the world’s productive systems continued to be heavily centered on agricultural production throughout this period, major changes occurred in agricultural labor, the systems and locations of manufacturing, gender and social structures, and environmental processes. So go to Windows Settings and check for updates. If you want to play Age of Empires IV without any issues, you should keep Windows up to date. You can find the latest drivers for Nvidia, AMD, and Intel:Īudio drivers are also important. GeForce Game Ready driver (Version: 496.49) delivers optimizations and enhancements for Age of Empires 4. Nvidia has already released a new driver. Make sure your graphics drivers are up to date. Click "Verify integrity of game files." 4.The option to repair game files is currently not available in the Microsoft Store (Xbox app). After that, verify the Age of Empires 4's files by following the steps of the next method (if on Steam) 3. ![]() Navigate to This PC\Documents\My Games\Age of Empires IV.If your AOE4 crashes during gameplay, deleting the configuration file may help fix it. On Global Settings, select High-performance NVIDIA processor as Preferred graphics processor.You can similarly set it up by selecting your preferred video card in the Nvidia Control Panel. Note: Here's how to find AoEIV's file location on Steam: Steam Library > Right-click on Age of Empires IV > Manage > Browse local filesĭefault path "C:\Program Files (x86)\Steam\steamapps\common\Age of Empires IV\RelicCardinal.exe" Microsoft Store (Game Pass) users: Click Browse > Change the dropdown from Desktop app to Microsoft Store app > Select Age of Empires IV from the second dropdown list > Add > Click Options > Set Graphics preference to High performance > Save Steam users: Click Browse > Select and Add the RelicCardinal.exe (AOE4’s exe) > Click Options > Set Graphics preference to High performance > Save.Press the Windows key on your keyboard, and type graphics settings. ![]() In Windows 10, you can easily fix the issue by following these steps: ![]() ![]() ![]() rights may not apply to contracts between you and this publisher. The Greatest Penguin Heist of All Time > Guides > s Guides. You’ll experience a blend of physics-based platforming with stealth, strategy, action, and CHAOS. All Discussions Screenshots Artwork Broadcasts Videos News Guides Reviews. ![]() ![]() This is a collaborative community website about The Greatest Penguin Heist Of All Time that anyone, including you, can join and help to expand. The Greatest Penguin Heist of All Time is the one and only 1-8 player CO-OP physics-based heist game featuring a bunch of kleptomanic penguins. The Greatest Penguin Heist of All Time Video Game VideoGameGeek Skip Navigation Accessibility Feedback Browse Forums GeekLists Shopping Community Help Sign In Join (it's free) Skip Sidebar The Hotness Games F.I.S.T. Youll experience a blend of physics-based platforming with stealth and strategy, with full freedom to achieve the missions in your own way. Download The Greatest Penguin Heist of All Time Build 24072022 + OnLine 4) No need to. Welcome to the The Greatest Penguin Heist Of All Time Wiki Nooting, Shooting, Penguins. Last night she dreamt that her dad, the brilliant but slightly odd Professor Dexter, had been trapped in a nightmare by his evil boss Lilith Delamere!īut it's not just a dream - it's real and Maya and her new friends the Dream Bandits must rescue the Professor before it's too late! All they need is a bit of courage and a LOT of imagination. Summary: The Greatest Penguin Heist of All Time is the one and only 4 player CO-OP physics-based heist game featuring a bunch of kleptomanic penguins. The Greatest Penguin Heist of All Time System requirements Minimum system requirements 64bit support Yes System requirements Windows 10 Processor Dual Core 2. Have you ever had a really strange dream? Maya Clayton definitely has. Radio 1 broadcasters and bestselling authors of KID NORMAL - Greg James and Chris Smith - are back with a mind-bending adventure you won't want to wake up from. ![]() ![]() ![]() Run S-NWU_-010101WF-ALLIN-ALL_.exe to launch the installer.Download S-NWU_-010101WF-ALLIN-ALL_.exe to the folder created in Step 1.Create a folder on the hard disk and name it as desired.Added support for Z 9 firmware version 2.00.All other trade names mentioned are trademarks or registered trademarks of their respective holders.Windows is a registered trademark of Microsoft Corporation in the United States and other countries.When Webcam Utility is accessed from multiple web conferencing apps simultaneously, live view will be available to only one app.If the Nikon Webcam Utility is chosen as the video input source while NX Tether, Camera Control Pro 2, or Nikon Transfer 2 is running, a connection to the camera will not be established and the view through the camera lens will not be displayed.Live view may take more time to start if the memory card contains a large number of pictures.When using the D5, D810, D750, D500, D7500, D7200, D5600, D5500, D5300, or D3500 with no memory card inserted, select Enable release for Slot empty release lock.Extend retractable lenses before use.PC mode can be ended by disconnecting the USB cable. The camera may not exit PC mode when the web conferencing app closes.Live view may not end when the camera is turned off and then on again, in which case it can be ended by turning the camera on and off a second time.Live view may not end automatically when the live view auto off timer expires.Once a connection has been established between the camera and computer, be careful not to remove the memory card while the memory card access lamp is lit.Some web conferencing apps may use different aspect ratios. The frame size is 1024 x 768 pixels (XGA).Before adjusting settings, turn the camera off and disconnect the USB cable. You may not be able to adjust camera settings while the camera is connected to a computer.When using NX Tether, Nikon Transfer 2, or Camera Control Pro 2, end the connection to “Webcam Utility” in the web conferencing app. ![]()
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